Newly released WPF MVVM Toolkit : http://wpf.codeplex.com/Wiki/View.aspx?title=WPF%20Model-View-ViewModel%20Toolkit
An Advanced MSDN Article explaining the MVVM Pattern: http://msdn.microsoft.com/en-us/magazine/dd419663.aspx
And a Channel 9 Video about MVVM: http://channel9.msdn.com/shows/Continuum/MVVM/
Emad's Blog 
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